WEB The most shocking moment in FIFA World Cup history When France and Italy were locked in a stalemate deep in extra-time in the 2006 Final Zinedine Zidane st. WEB In the 2006 World Cup Final Frances best player Zinedine Zidane was shown a red card after headbutting Italian midfielder Marco Materazzi in the. WEB BBC Sport looks back to one of the most infamous moments in World Cup history when France captain Zinedine Zidane headbutted Italys. . Read about and watch footage of Zinedine Zidanes last act as a player An infamous headbutt on Marco Materazzi in the Germany 2006 final..
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